Kinetics of oxidation of allyl alcohol by chloramine-T in hydrochloric acid medium: effect of high acid concentrations
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چکیده
منابع مشابه
Kinetics and Mechanistic Study of Oxidation of Amoxicillin by Chloramine-t in Acid Medium
This spectroscopic study presents the kinetics and degradation pathways of oxidation of amoxicillin (AMOX) by chloramines-T (CAT) in acidic medium at a constant ionic strength of 0.105 mol dm-3 at 298 K. Reaction between AMOX and CAT in acidic medium exhibits 1:1 stoichiometry (AMOX:CAT). The reaction is of a first-order in both [CAT] and [AMOX]. The order with respect to acid concentration was...
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The kinetics of oxidation of allyl alcohol by quinaldinium chlorochromate is investigated in 40 % acetic acid – water (v/v) medium. The order with respect to oxidant and hydrogen ion concentration is found to be one and fractional with respect to substrate. The rate of the reaction is decreases with the decrease in the dielectric constant of the medium. The rate of the reaction has negligible e...
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ژورنال
عنوان ژورنال: Australian Journal of Chemistry
سال: 1975
ISSN: 0004-9425
DOI: 10.1071/ch9750899